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Platinum-coated Electrodes For Hydrogen Production
2. a small change in pole distance,
3. strong corrosion resistance,
4. good mechanical strength and processing performance,
5. long life, low cost,
6. and good electrocatalytic performance for electrode reaction.
Titanium anode is the anode in titanium-based metal oxide coating. According to the different
surface catalytic coatings, it has the function of oxygen evolution and chlorine evolution respectively.
Generally, electrode materials should have good electrical conductivity, a small change in pole
distance, strong corrosion resistance, good mechanical strength and processing performance, long life,
low cost, and good electrocatalytic performance for electrode reaction. Titanium is the most suitable
for the above comprehensive The required metal is generally industrial pure titanium GR1 OR GR2.
Classification
Soluble anodes and insoluble anodes
The soluble anode plays the role of supplementing metal ions and conducts electricity during the
electrolysis process, while the insoluble anode only plays the role of conducting electricity. The earliest
insoluble anodes were graphite and lead-based anodes. In the 1970s, titanium anodes began to be
used in electrolysis and electroplating as new technology. Insoluble anodes can be divided into two
categories: chlorine evolution anodes and oxygen evolution anodes. Chlorine evolution anode is
mainly used in chloride electrolyte systems. During the electroplating process, the anode releases
chlorine gas, so it is called a chlorine evolution anode; oxygen evolution anode is mainly used in
sulfate, nitrate, hydrocyanate, and other electrolyte systems. During the process, oxygen is released
from the anode, so it is called an oxygen evolution anode. Lead alloy anodes are oxygen-evolution
anodes and titanium anodes have oxygen-evolution, chlorine-evolution functions, or both according
to their surface catalytic coatings.
Titanium anode for the Chlor-alkali industry
Compared with the graphite electrode, the diaphragm method produces caustic soda, and the working
voltage of the graphite anode is 8A/DM2, which can be doubled to 17A/DM2. In this way, the product
can be doubled under the same electrolysis environment, the quality of the produced product is
high and the purity of chlorine gas is high.
Titanium anode for electroplating
Insoluble anodes for electroplating are coated with noble metal oxide coatings with high
electrochemical catalytic performance on titanium substrates (mesh, plate, ribbon, tubular, etc.), and
the coating contains valve metal oxides with high stability. The new insoluble titanium anode has high
electrochemical catalytic energy, and the oxygen evolution overpotential is about 0.5 V lower than that
of the lead alloy insoluble anode. The oxygen evolution overpotential of the new insoluble titanium
anode is also lower than that of the platinum-plated insoluble anode, but the life span is more than
doubled. It is widely used as an anode or auxiliary anode in various electroplating and can replace
conventional lead-based alloy anode. Under the same conditions, it can reduce cell voltage and save
power consumption; insoluble titanium anode has good stability in the electroplating process.
(chemical, electrochemical), long service life. This anode is widely used in nickel-plated gold-plated,
chrome-plated, zinc-plated, copper-plated, and other electroplating non-ferrous metal industries.
Lead and lead alloy anodes
The lead alloy anode belongs to the oxygen evolution anode, and the electrolyte for the oxygen
evolution reaction is sulfuric acid and sulfate, which is mainly used in electrolytic metallurgy. Such
anodes have the disadvantage that the geometry will change during electrolysis. , During the
electrolysis process, the lead anode matrix is first converted into lead sulfate and then into lead oxide.
Lead sulfate is an intermediate layer that acts as an insulator and acts as a
chemical barrier to protect the lead matrix of the inner layer in a sulfuric acid environment.
Lead oxide is an electrode in the actual sense in the outer layer, and an oxygen
evolution reaction occurs on it. The oxygen evolution potential of lead oxide is very high,
and it rises rapidly with the increase of current density. This feature of lead alloy anode
is that it is oxidized by its outer layer material. The inherent characteristics of lead-lead oxide are
determined by the poor conductor of electricity.
In addition, during the electrolysis process, the electrochemical performance of the lead oxide anode
structure is constantly attenuated, and the generation of internal stress causes the oxide layer to
fall off. In addition, the formation of lead peroxide also causes the continuous dissolution of the oxide,
and the sulfuric acid as the intermediate layer The lead is converted into lead oxide again and
becomes a new electrocatalytic active material of the outer oxide, and the lead matrix of the inner
the layer is oxidized again to form a new intermediate a protective layer of lead sulfate. Therefore,
during the electrolysis process, lead and its alloying elements are continuously dissolved into the
electrolyte and precipitated, resulting in solution pollution (chemical precipitation in the solution) and
pollution of cathode products(electrodeposition of pollutants on the surface of the cathode, and the
purity of electrolysis to copper cannot be very high. good is guaranteed).
Coated Titanium Anode
Coated titanium anode, commonly known as DSA (Dimensionally Stable Anode), also known as DSE
(Dimensionally Stable Electrode), is a new type of insoluble anode material developed in the late
The 1960s.
DSA-coated titanium anodes are mainly used in electrochemistry and electrometallurgy.
The fields of application of DSA-coated titanium anodes are the Chlor-alkali industry, chlorate
production, hypochlorite production, perchlorate production, persulfate electrolysis, electrolytic
organic synthesis, electrolytic extraction of non-ferrous metals, electrolytic silver catalyst production,
Copper foil production by electrolysis, mercury recovery by electrolytic oxidation, water electrolysis,
production of chlorine dioxide, hospital sewage treatment, treatment of cyanide-containing
wastewater in electroplating plants, disinfection of domestic water and food utensils, treatment of
cooling circulating water in power plants, wool spinning Treatment of factory dyeing, and finishing
wastewater, treatment of industrial water, production of acid-base ionized water by electrolysis,
galvanizing, rhodium-plating, palladium-plating, gold-plating, lead-plating of copper plates,
desalination of seawater by electrodialysis, preparation of tetramethyl hydroxide by electrodialysis
Ammonium, molten salt electrolysis, battery production, cathodic protection, production of negative
electrode foil, anodization of aluminum foil, etc. It is widely used in the chemical industry, metallurgy,
water treatment, environmental protection, electroplating, electrolytic organic synthesis, and other
fields.
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